Italy

Francesco Totti delivers a cold-blooded penalty against Australia in the 2006 World Cup Round of 16, sending Italy into the quarterfinals in dramatic fashion. In stoppage time, with the match heading toward extra time, he steps up under immense pressure and buries a powerful shot into the top corner, leaving the goalkeeper no chance. His composure, precision, and leadership in a decisive moment make this one of the most iconic penalties in Italian football history. This goal fuels Italy’s path to eventual World Cup glory.